Lanthanide(III) nitrate adducts with 2,6-dimethyl-4H-pyran-4-one
Journal Article
·
· Journal of Coordination Chemistry; (USA)
- Istituto di Chimica e Tecnologia die Radioelement del C.N.R., Padova (Italy)
- Metallorganica ed Analitica dell'Universita, Padova (Italy)
The new lanthanide complexes (Ln(DMP){sub 3}(NO{sub 3}){sub 3}) (Ln = La, C, Pr, Nd, Sm, Eu or Gd; DMP = 2,6-dimethyl-4H-pyran-4-one) and Ln(DMP){sub 2}(H{sub 2}O){sub 2}(NO{sub 3}){sub 3}. H{sub 2}o (Ln = La or Ce) have been characterized by spectroscopic (infrared, {sup 1}H nmr, {sup 13}C nmr) and thermogravimetric data. Moreover the uranyl adducts (UO{sub 2}(DMP){sub 2}(NO{sub 3}){sub 2}) and (UO{sub 2}(DMP)(O{sub 2}CMe){sub 2}) have been isolated. The influence of the solvent on the reaction products is discussed.
- OSTI ID:
- 6903310
- Journal Information:
- Journal of Coordination Chemistry; (USA), Journal Name: Journal of Coordination Chemistry; (USA) Vol. 20:2; ISSN JCCMB; ISSN 0095-8972
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
36 MATERIALS SCIENCE
360100 -- Metals & Alloys
360104 -- Metals & Alloys-- Physical Properties
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400000* -- Chemistry
400201 -- Chemical & Physicochemical Properties
ACTINIDE COMPLEXES
CALCULATION METHODS
COMPLEXES
DATA
DATA ANALYSIS
EXPERIMENTAL DATA
INFORMATION
INFRARED SPECTRA
LANTHANUM COMPLEXES
MAGNETIC RESONANCE
MEASURING INSTRUMENTS
MEASURING METHODS
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
RARE EARTH COMPLEXES
RESONANCE
SPECTRA
THERMOGRAPHY
URANIUM COMPLEXES
URANYL COMPLEXES
360100 -- Metals & Alloys
360104 -- Metals & Alloys-- Physical Properties
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400000* -- Chemistry
400201 -- Chemical & Physicochemical Properties
ACTINIDE COMPLEXES
CALCULATION METHODS
COMPLEXES
DATA
DATA ANALYSIS
EXPERIMENTAL DATA
INFORMATION
INFRARED SPECTRA
LANTHANUM COMPLEXES
MAGNETIC RESONANCE
MEASURING INSTRUMENTS
MEASURING METHODS
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
RARE EARTH COMPLEXES
RESONANCE
SPECTRA
THERMOGRAPHY
URANIUM COMPLEXES
URANYL COMPLEXES