Lanthanide(III) nitrate adducts with 2,6-dimethyl-4H-pyran-4-one

Journal Article · Sat Jul 01 00:00:00 EDT 1989 · Journal of Coordination Chemistry; (USA)

DOI:https://doi.org/10.1080/00958978909408866· OSTI ID:6903310

Sitran, S; Fregona, D ^[1]; Faraglia, G ^[2]

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1. Istituto di Chimica e Tecnologia die Radioelement del C.N.R., Padova (Italy)
2. Metallorganica ed Analitica dell'Universita, Padova (Italy)

The new lanthanide complexes (Ln(DMP){sub 3}(NO{sub 3}){sub 3}) (Ln = La, C, Pr, Nd, Sm, Eu or Gd; DMP = 2,6-dimethyl-4H-pyran-4-one) and Ln(DMP){sub 2}(H{sub 2}O){sub 2}(NO{sub 3}){sub 3}. H{sub 2}o (Ln = La or Ce) have been characterized by spectroscopic (infrared, {sup 1}H nmr, {sup 13}C nmr) and thermogravimetric data. Moreover the uranyl adducts (UO{sub 2}(DMP){sub 2}(NO{sub 3}){sub 2}) and (UO{sub 2}(DMP)(O{sub 2}CMe){sub 2}) have been isolated. The influence of the solvent on the reaction products is discussed.

• OSTI ID: 6903310
• Journal Information: Journal of Coordination Chemistry; (USA), Vol. 20:2; ISSN 0095-8972
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
LANTHANUM COMPLEXES
INFRARED SPECTRA
NUCLEAR MAGNETIC RESONANCE
URANYL COMPLEXES
CALCULATION METHODS
DATA ANALYSIS
EXPERIMENTAL DATA
MEASURING INSTRUMENTS
MEASURING METHODS
THERMOGRAPHY
ACTINIDE COMPLEXES
COMPLEXES
DATA
INFORMATION
MAGNETIC RESONANCE
NUMERICAL DATA
RARE EARTH COMPLEXES
RESONANCE
SPECTRA
URANIUM COMPLEXES
400000* - Chemistry
360100 - Metals & Alloys
360104 - Metals & Alloys- Physical Properties
400201 - Chemical & Physicochemical Properties