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Thermal-shock studies on refractories for slagging coal gasifiers

Technical Report ·
OSTI ID:6878743
Water quench tests and ribbon tests were used to investigate the thermal-shock resistance of several commercial refractories that are candidates for use in slagging coal-gasifier linings. Both tests allowed ranking of the refractories with respect to thermal-shock resistance, and indicated that refractories with high alumina content generally have better resistance than those with high chromia content. The nature (discontinuous vs gradual) of the observed strength degradation for a single-cycle water quench was found to be in general agreement with that predicted from the calculated crack length by measuring the critical stress intensity factor (K/sub Ic/) and strength (sigma/sub f/). The thermal-shock-resistance parameter R/sub st/ was found to provide a good measure of the thermal-shock-damage resistance in the ribbon test. However, a microstructural evaluation is necessary to select a particular parameter for predicting the degradation of refractories by thermal shock. The retained elastic modulus after thermal shock increased rapidly with increasing R/sub st/ up to a critical value of R/sub st/; above this critical value, the increase in the modulus with further increases in R/sub st/was relatively small. These results are discussed in terms of their implications for the selection and development of new refractories with improved thermal-shock resistance.
Research Organization:
Argonne National Lab., IL (USA)
DOE Contract Number:
W-31109-ENG-38
OSTI ID:
6878743
Report Number(s):
ANL/FE-84-3; ON: DE84016352
Country of Publication:
United States
Language:
English

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