Effect of sorbent attrition on utilization
- Cincinnati Univ., OH (United States)
During this period, the project has focused on two aspects of attrition; (1) mechanical attrition which is responsible for particle fracture whenever particles are moving with respect to a fixed reference frame, and (2) chemical attrition which can be responsible for particle fracture whenever particles undergo reactions. The experiments were conducted with calcium based sorbent materials. Two specific project objectives were identified and studied. The first of these was to determine the effect of temperature, particle velocity, and particle surface area on the extent of attrition in a circulating fluidized reactor. The second was to investigate if attrition could improve sorbent utilization of typical calcium based sorbents of small size (<20 [mu]m). A sample of sulfated calcium hydroxide sorbent was obtained for attrition tests in a circulating fluidized bed reactor. Attempts at attriting this material in the fluidized bed were not successful, and no improvements in sorbent utilization were measured in subsequent TGA tests with the solids. However, an analysis of the other constituents in the particles revealed that a major portion of the hydroxide had been converted to calcium carbonate. This gave rise to the possibility that dolomitic hydroxide may have characteristics which may be beneficial and that improvements in utilization could be realized by means of chemical attrition. This is due to the thermal instability of magnesium carbonate at temperatures above 650[degree]F which means that magnesium oxide will be the major unreacted magnesium species in spent sorbent.
- Research Organization:
- Ohio Coal Development Office, Columbus, OH (United States); Cincinnati Univ., OH (United States)
- Sponsoring Organization:
- STOFOH; Ohio State Government, Columbus, OH (United States)
- OSTI ID:
- 6871335
- Report Number(s):
- OCDO-93006589; ON: TI93006589; CNN: CDO/R-87-2C/B
- Country of Publication:
- United States
- Language:
- English
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ALKALINE EARTH METAL COMPOUNDS
CALCIUM COMPOUNDS
CALCIUM HYDROXIDES
CARBON COMPOUNDS
CARBONATES
CHALCOGENIDES
CHEMICAL ANALYSIS
CHEMICAL REACTIONS
CIRCULATING SYSTEMS
DESULFURIZATION
DOCUMENT TYPES
DRY SCRUBBERS
EQUIPMENT
FLUE GAS
FLUIDIZED BEDS
FOSSIL-FUEL POWER PLANTS
FRAGMENTATION
GASEOUS WASTES
GRAVIMETRIC ANALYSIS
HYDROGEN COMPOUNDS
HYDROXIDES
MAGNESIUM CARBONATES
MAGNESIUM COMPOUNDS
MAGNESIUM HYDROXIDES
MAGNESIUM OXIDES
OXIDES
OXYGEN COMPOUNDS
PARTICLES
PARTICULATES
POLLUTION CONTROL EQUIPMENT
POWER PLANTS
PROGRESS REPORT
QUANTITATIVE CHEMICAL ANALYSIS
SCRUBBERS
SURFACE AREA
SURFACE PROPERTIES
TEMPERATURE EFFECTS
THERMAL ANALYSIS
THERMAL GRAVIMETRIC ANALYSIS
THERMAL POWER PLANTS
VELOCITY
WASTES