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X ray absorption spectra of ruthenium L edges in Ru(NH/sub 3/)/sub 6/Cl/sub 3/

Conference ·
OSTI ID:6869715
The three L edges of Ru in Ru(NH/sub 3/)/sub 6/Cl/sub 6/ yield information on the distribution of the density of states of the unoccupied molecular orbitals. The dipole transition intensities were calculated. The splitting of the p..-->..d transition at the L/sub III/ edge is used to calculate the crystal field 10 Dq parameter of Ru (NH/sub 3/)/sub 6/ Cl/sub 3/ to be 3.93 eV. (DLC)
Research Organization:
Brookhaven National Lab., Upton, NY (USA)
DOE Contract Number:
AC02-76CH00016
OSTI ID:
6869715
Report Number(s):
BNL-31866; CONF-820957-1; ON: DE83000244
Country of Publication:
United States
Language:
English