X-ray absorption spectra of ruthenium L edges in Ru(NH/sub 3/)/sub 6/Cl/sub 3/

Journal Article · Wed Apr 20 04:00:00 EST 1983 · J. Am. Chem. Soc.; (United States)

DOI:https://doi.org/10.1021/ja00346a028· OSTI ID:5833780

Sham, T K

X-ray absorption spectra of ruthenium L edges of (Ru(NH/sub 3/)/sub 6/)Cl/sub 3/ have been obtained with synchrotron radiation. It is found that Ru L edges exhibit white lines characteristic of ligand-field and spin-orbit effects. Analysis of the data on the basis of local symmetry and the electronic configuration of the complex yields a 10Dq value of 3.93 eV.

• Research Organization: Brookhaven National Lab., Upton, NY
• OSTI ID: 5833780
• Journal Information: J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 105:8; ISSN JACSA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AMMONIA
BINDING ENERGY
BREMSSTRAHLUNG
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
COUPLING
CRYSTAL FIELD
CRYSTAL STRUCTURE
ELECTROMAGNETIC RADIATION
ELECTRONIC STRUCTURE
ENERGY
HALIDES
HALOGEN COMPOUNDS
HYDRIDES
HYDROGEN COMPOUNDS
INTERMEDIATE COUPLING
L-S COUPLING
MOLECULAR ORBITAL METHOD
NITROGEN COMPOUNDS
NITROGEN HYDRIDES
RADIATIONS
RUTHENIUM COMPLEXES
SPECTRA
SYMMETRY
SYNCHROTRON RADIATION
TRANSITION ELEMENT COMPLEXES
X-RAY SPECTRA