Infrared-laser-induced organic reactions. Technical progress report. [Vinycyclopropane; bicyclopropyl and bicyclopropyl-d/sub 4/; diethylcarbonate-d/sub 5/; t-butyl hydroperoxide; oxetane; 2-propanol]
Technical Report
·
OSTI ID:6869470
Experiments of two types have been conducted. In the first, competition among activation, deactivation, and unimolecular chemical reaction in laser-irradiated organic vapors were investigated. The following compounds were studied: vinycyclopropane; bicyclopropyl and bicyclopropyl-d/sub 4/; diethylcarbonate-d/sub 5/. As an outgrowth of these experiments, single photon vibrational overtone excitation of t-butyl hydroperoxide was initiated. In the second phase of this program, infrared laser activation of mechanistically more complex reactions were studied. These were laser-induced decomposition of 2-propanol catalyzed by CuO, and laser-induced decomposition of oxetane. Results are discussed.
- Research Organization:
- Minnesota Univ., Minneapolis (USA). Dept. of Chemistry
- DOE Contract Number:
- AC02-80ER10592
- OSTI ID:
- 6869470
- Report Number(s):
- DOE/ER/10592-3; ON: DE83000285
- Country of Publication:
- United States
- Language:
- English
Similar Records
Infrared laser induced organic reactions. [Vinylcycloprane; diethylcarbonate-d5; oxetane]
Infrared laser induced organic reactions. Technical progress report, October 15, 1980
Comparison of overtone-induced and electronic photochemistry of liquid tert-butyl hydroperoxide: supporting evidence for vibrational mode selectivity
Technical Report
·
Thu Oct 15 00:00:00 EDT 1981
·
OSTI ID:5455466
Infrared laser induced organic reactions. Technical progress report, October 15, 1980
Technical Report
·
Fri Feb 29 23:00:00 EST 1980
·
OSTI ID:6904060
Comparison of overtone-induced and electronic photochemistry of liquid tert-butyl hydroperoxide: supporting evidence for vibrational mode selectivity
Journal Article
·
Wed Jan 13 23:00:00 EST 1988
· J. Phys. Chem.; (United States)
·
OSTI ID:5476945
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
ALCOHOLS
ALKANES
CARBON DIOXIDE LASERS
CARBONIC ACID ESTERS
CHALCOGENIDES
CHEMISTRY
COPPER COMPOUNDS
COPPER OXIDES
CYCLOALKANES
DEUTERIUM COMPOUNDS
ESTERS
GAS LASERS
HETEROCYCLIC OXYGEN COMPOUNDS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INFRARED SPECTRA
IRRADIATION
LASERS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PEROXIDES
PHOTOCHEMISTRY
PROPANOLS
PULSED IRRADIATION
RESEARCH PROGRAMS
SPECTRA
TRANSITION ELEMENT COMPOUNDS
400500* -- Photochemistry
ALCOHOLS
ALKANES
CARBON DIOXIDE LASERS
CARBONIC ACID ESTERS
CHALCOGENIDES
CHEMISTRY
COPPER COMPOUNDS
COPPER OXIDES
CYCLOALKANES
DEUTERIUM COMPOUNDS
ESTERS
GAS LASERS
HETEROCYCLIC OXYGEN COMPOUNDS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INFRARED SPECTRA
IRRADIATION
LASERS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PEROXIDES
PHOTOCHEMISTRY
PROPANOLS
PULSED IRRADIATION
RESEARCH PROGRAMS
SPECTRA
TRANSITION ELEMENT COMPOUNDS