Infrared laser induced organic reactions. [Vinylcycloprane; diethylcarbonate-d5; oxetane]
Technical Report
·
OSTI ID:5455466
Experiments of two types were carried out. In the first, the objective was to develop a complete understanding of the competition among activation, deactivation and unimolecular chemical reaction in laser-irradiated organic vapors. The following compounds were studied; vinylcyclopropane; bicyclopropyl-d4; diethylcarbonate-d5. Details of these investigations are provided. As an outgrowth of these experiments, single photon vibrational overtone excitation of organic molecules was also investigated. In the second phase of this program, infrared laser activation of mechanistically more complex reactions were investigated. These were laser-induced reactions in gas/solid mixtures (surface chemistry of graphite and 2-propanol/CuO), and laser-induced chemicluminescence (octane decomposition). Results are discussed.
- Research Organization:
- Minnesota Univ., Minneapolis (USA). Dept. of Chemistry
- DOE Contract Number:
- AC02-80ER10592
- OSTI ID:
- 5455466
- Report Number(s):
- DOE/ER/10592-T1; ON: DE82007951
- Country of Publication:
- United States
- Language:
- English
Similar Records
Infrared-laser-induced organic reactions. Technical progress report. [Vinycyclopropane; bicyclopropyl and bicyclopropyl-d/sub 4/; diethylcarbonate-d/sub 5/; t-butyl hydroperoxide; oxetane; 2-propanol]
Infrared laser induced organic reactions. Technical progress report, October 15, 1980
Thermal unimolecular decomposition of bicyclopropyl and deuterated analogues: infrared photoactivation as a diagnostic tool in mechanistic organic chemistry
Technical Report
·
Tue Sep 07 00:00:00 EDT 1982
·
OSTI ID:6869470
Infrared laser induced organic reactions. Technical progress report, October 15, 1980
Technical Report
·
Fri Feb 29 23:00:00 EST 1980
·
OSTI ID:6904060
Thermal unimolecular decomposition of bicyclopropyl and deuterated analogues: infrared photoactivation as a diagnostic tool in mechanistic organic chemistry
Journal Article
·
Thu Dec 02 23:00:00 EST 1982
· J. Org. Chem.; (United States)
·
OSTI ID:6347381
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
ALCOHOLS
ALKANES
CARBON
CARBON DIOXIDE LASERS
CARBONIC ACID ESTERS
CHALCOGENIDES
CHEMISTRY
COPPER COMPOUNDS
COPPER OXIDES
CYCLOALKANES
DEUTERIUM COMPOUNDS
ELEMENTAL MINERALS
ELEMENTS
ESTERS
GAS LASERS
GRAPHITE
HETEROCYCLIC OXYGEN COMPOUNDS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INFRARED SPECTRA
IRRADIATION
LASERS
MINERALS
MOLECULAR STRUCTURE
NONMETALS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHOTOCHEMISTRY
PROPANOLS
PULSED IRRADIATION
RESEARCH PROGRAMS
SPECTRA
TRANSITION ELEMENT COMPOUNDS
400500* -- Photochemistry
ALCOHOLS
ALKANES
CARBON
CARBON DIOXIDE LASERS
CARBONIC ACID ESTERS
CHALCOGENIDES
CHEMISTRY
COPPER COMPOUNDS
COPPER OXIDES
CYCLOALKANES
DEUTERIUM COMPOUNDS
ELEMENTAL MINERALS
ELEMENTS
ESTERS
GAS LASERS
GRAPHITE
HETEROCYCLIC OXYGEN COMPOUNDS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INFRARED SPECTRA
IRRADIATION
LASERS
MINERALS
MOLECULAR STRUCTURE
NONMETALS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHOTOCHEMISTRY
PROPANOLS
PULSED IRRADIATION
RESEARCH PROGRAMS
SPECTRA
TRANSITION ELEMENT COMPOUNDS