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Title: Crystal growth and properties of the RBa sub 2 Cu sub 3 O sub 7 minus y family

Journal Article · · Superconductivity; (USA)
OSTI ID:6862078
; ;  [1]
  1. M. V. Lomonosov Moscow State University, Moscow (SU)

The RBa{sub 2}Cu{sub 2}O{sub 7{minus}y} single crystals (R=Y, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, and Yb) with dimensions from 1--2 mm to 7--8 mm were grown from nonstoichiometric melts of R{sub 2}O{sub 3}-BaO-CuO systems. The growth mechanism seems to be a dislocation mechahism in which the substance is transported along a thin cuprate melt film which west the faces of the growing crystal. The domain structure depends on the growth conditions. In some cases nearly single-domain crystals of YBa{sub 2}Cu{sub 3}O{sub 7{minus}x} and TmBa{sub 2}Cu{sub 3}O{sub 7{minus}y} several millimeters in size can be obtained. Magnetic measurements were used to detect superconducting transitions. After annealing in oxygen the critical temperature increased to temperatures in the range 62--89 K for various metals.

OSTI ID:
6862078
Journal Information:
Superconductivity; (USA), Vol. 2:2
Country of Publication:
United States
Language:
English