Calculation of thermodynamic properties of multicomponent ionic reciprocal systems
Journal Article
·
· J. Chem. Phys.; (United States)
Thermodynamic properties of multicomponent ionic reciprocal systems are derived using the conformal ionic solution theory. The equations obtained are more general than previous equations and depend solely on the properties of the components and on those of the binary subsystems. The behavior of dilute solutions is carefully studied leading to a priori predictions of solubility products in multicomponent systems. The solubility products and the specific bond free energy for making an ion pair, e.g., the pair (A--X) in the binary solvent BY--CY, are shown to depend upon specific ionic interactions in the binary subsystems. The equations presented are compared with equations derived from prior theories.
- Research Organization:
- Argonne National Laboratory, Argonne, Illinois 60439
- DOE Contract Number:
- W-31109-ENG-38
- OSTI ID:
- 6848530
- Journal Information:
- J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 73:11; ISSN JCPSA
- Country of Publication:
- United States
- Language:
- English
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