Computer-aided design of molecular catalysts for alkane oxidation using dodeca-substituted iron porphyrins. [801Halogenated dodeca-substituted iron-porphyrins]

Conference · Mon Oct 26 23:00:00 EST 1992

OSTI ID:6836686

Shelnutt, J A; Martinez, S L; Erkkila, K E

Recent progress in the design, synthesis, and activity testing of catalysts for partial oxidation of light alkanes is described. The first testing results for the designed halogenated dodeca-substituted iron-porphyrin catalysts are presented. The results validate the design goals selected and suggest improvements to the current catalyst designs.

• Research Organization: Sandia National Labs., Albuquerque, NM (United States)
• Sponsoring Organization: DOE; USDOE, Washington, DC (United States)
• DOE Contract Number: AC04-76DP00789
• OSTI ID: 6836686
• Report Number(s): SAND-92-2302C; CONF-920953--2; ON: DE93004046
• Country of Publication: United States
• Language: English

Related Subjects

10 SYNTHETIC FUELS
100200 -- Synthetic Fuels-- Production-- (1990-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ALKANES
CARBOXYLIC ACIDS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTIONS
DATA
DESIGN
EXPERIMENTAL DATA
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYDROXY COMPOUNDS
INFORMATION
METHANE
METHANOL
NUMERICAL DATA
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDATION
PERFORMANCE TESTING
PORPHYRINS
SYNTHESIS
TESTING