Phase diagram of the system Bi/sub 2/O/sub 3/-MoO/sub 3/
Journal Article
·
· J. Catal.; (United States)
OSTI ID:6821593
- Nagasaki Univ.
The phase diagram of the system Bi/sub 2/0/sub 3/-MoO/sub 3/, which catalyzes the partial oxidation of olefins to unsaturated aldehydes or nitriles or to dienes, was studied by X-ray diffraction and differential thermal analysis. Eight compounds were identified in the bismuth-molybdenum range from 14:1 (7Bi/sub 2/O/sub 3/.MoO/sub 3/) to 2:3 (Bi/sub 2/O/sub 3/.3MoO/sub 3/). The correspondence of these compounds to catalyst compositions reported in literature was analyzed.
- OSTI ID:
- 6821593
- Journal Information:
- J. Catal.; (United States), Journal Name: J. Catal.; (United States) Vol. 58:3; ISSN JCTLA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
BISMUTH COMPOUNDS
BISMUTH OXIDES
CATALYSTS
CHALCOGENIDES
CHEMICAL COMPOSITION
CHEMICAL REACTIONS
COMPARATIVE EVALUATIONS
DIAGRAMS
HYDROCARBONS
MOLYBDENUM COMPOUNDS
MOLYBDENUM OXIDES
ORGANIC COMPOUNDS
OXIDATION
OXIDES
OXYGEN COMPOUNDS
PHASE DIAGRAMS
STRUCTURAL CHEMICAL ANALYSIS
TRANSITION ELEMENT COMPOUNDS
USES
400201* -- Chemical & Physicochemical Properties
ALKENES
BISMUTH COMPOUNDS
BISMUTH OXIDES
CATALYSTS
CHALCOGENIDES
CHEMICAL COMPOSITION
CHEMICAL REACTIONS
COMPARATIVE EVALUATIONS
DIAGRAMS
HYDROCARBONS
MOLYBDENUM COMPOUNDS
MOLYBDENUM OXIDES
ORGANIC COMPOUNDS
OXIDATION
OXIDES
OXYGEN COMPOUNDS
PHASE DIAGRAMS
STRUCTURAL CHEMICAL ANALYSIS
TRANSITION ELEMENT COMPOUNDS
USES