Electrocatalytic hydroxylation of alkanes and identification of a fluoroiron(V) porphyrin intermediate
Journal Article
·
· Journal of the American Chemical Society; (USA)
- Univ. of Iowa, Iowa City (USA)
High-valent iron porphyrin models for the active intermediate in the cytochrome P-450 cycle have been generated and used as catalysts for the selective epoxidation of alkenes and hydroxylation of alkanes. This work describes the electrocatalytic hydroxylation of cyclohexane with the difluoroiron (III) 2,6-difluorotetraphenylporphyrin anionic complex, ((F8-TPP)FeF{sub 2}{sup {minus}}). Magnetic resonance and optical spectroscopic measurements have been used to elucidate the electronic structure of the product formed following oxidation of (F8-TPP)FeF{sub 2}{sup {minus}} by m-chloroperbenzoic acid (MCPBA) in the presence of excess fluoride ion.
- OSTI ID:
- 6811996
- Journal Information:
- Journal of the American Chemical Society; (USA), Journal Name: Journal of the American Chemical Society; (USA) Vol. 112:10; ISSN 0002-7863; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKANES
CARBOXYLIC ACIDS
CATALYSTS
DATA
DATA ANALYSIS
ELECTROCATALYSTS
EXPERIMENTAL DATA
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYDROXYLATION
INFORMATION
MEASURING METHODS
NUMERICAL DATA
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PORPHYRINS
400201* -- Chemical & Physicochemical Properties
ALKANES
CARBOXYLIC ACIDS
CATALYSTS
DATA
DATA ANALYSIS
ELECTROCATALYSTS
EXPERIMENTAL DATA
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYDROXYLATION
INFORMATION
MEASURING METHODS
NUMERICAL DATA
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PORPHYRINS