Reactions of germanium tetrahalides with ketene acetals

Journal Article · Wed May 01 00:00:00 EDT 1985 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6811099

Efimova, I V; Kazankova, M A; Lutsenko, I F

Recently, the authors reported that alkyl vinyl ethers and terminal alkynes are readily germylated by germanium tetrahalides in the presence of a tertiary amine. To extend the range of applicability of this reaction and to obtain additional information on its mechanism, the authors study reactions of ketene acetals with germanium tetrachloride and tetrabromide in the presence of triethylamine.

• Research Organization: M.V. Lomonosov Moscow State Univ.
• OSTI ID: 6811099
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 54:11, PT. 2; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACETALS
ALKYNES
AMINES
BROMIDES
BROMINE COMPOUNDS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHLORIDES
CHLORINE COMPOUNDS
ETHERS
GERMANIUM BROMIDES
GERMANIUM CHLORIDES
GERMANIUM COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HIGH TEMPERATURE
HYDROCARBONS
KETENES
KINETICS
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
QUANTITY RATIO
REACTION KINETICS
SPECTRA
SYNTHESIS
YIELDS