Reaction of the oximes of aliphatic aldehydes and ketones with alkoxyethenes
In the reaction of acetone oxime with alkyl vinyl ethers in the presence of zinc chloride variable amounts of acetone 0,0'-(2-propylidene)dioxime, acetaldehyde dialkyl acetal, acetaldehyde 0-(1-alkoxyethyl)oxide, and acetone 0-(1-alkoxy-1-methylethyl)oxime, depending on the reaction conditions, are formed in addition to acetone 0-(1-alkoxyethyl)oxime (the initial addition product). In the reaction of acetaldehyde oxime with alkyl vinyl ethers in the presence of zinc chloride acetaldehyde oxime with alkyl vinyl ethers in the presence of zinc chloride acetaldehyde dialkyl acetal was isolated in addition to acetaldehyde 0-(1-alkoxyethyl)oxime. A mechanism for the formation of the obtained compounds is proposed.
- Research Organization:
- Irkutsk Institute of Organic Chemistry, USSR
- OSTI ID:
- 6286873
- Journal Information:
- J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 23:1; ISSN JOCYA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Reactions and reaction intermediates on iron surfaces. III. Reactions of aldehydes and ketones on Fe(100)
Reactions of germanium tetrahalides with ketene acetals
Related Subjects
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACETALDEHYDE
ACETALS
ACETONE
ACTIVATION ENERGY
ALDEHYDES
AMINES
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL SHIFT
CHLORIDES
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINE COMPOUNDS
CHLOROFORM
CHROMATOGRAPHY
COUPLING
COUPLING CONSTANTS
DEUTERIUM COMPOUNDS
ENERGY
ETHERS
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HETEROGENEOUS CATALYSIS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
HYPERFINE STRUCTURE
INTERMEDIATE COUPLING
J-J COUPLING
KETONES
NMR SPECTRA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIMES
SEPARATION PROCESSES
SPECTRA
YIELDS
ZINC CHLORIDES
ZINC COMPOUNDS
ZINC HALIDES