Electrochemical behavior of Cu(II)-poly(4-vinylpyridine) complexes at the electrode/electrolyte interface
Journal Article
·
· Sov. Electrochem. (Engl. Transl.); (United States)
OSTI ID:6801191
The electrochemical behavior and electrocatalytic properties of the complex of Cu/sup 2 +/ with poly(4-vinylpyridine) were studied at a pyrolytic graphite electrode. It was shown that not all copper ions of the polymer films are in an electrochemically active state when the process is conducted under nonequilibrium conditions. The counterion type has an important effect of the electrochemical behavior of the polymer film electrode. The complex displays electrocatalytic activity in molecular-oxygen electroreduction in neutral buffer solutions; the activity depends on the degree of saturation of the polymer film with copper ions.
- Research Organization:
- A. N. Frumkin Institute of Electrochemistry, Moscow, USSR
- OSTI ID:
- 6801191
- Journal Information:
- Sov. Electrochem. (Engl. Transl.); (United States), Journal Name: Sov. Electrochem. (Engl. Transl.); (United States) Vol. 22:6; ISSN SOECA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400400 -- Electrochemistry
AZINES
CARBON
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
COPPER COMPLEXES
ELECTROCATALYSTS
ELECTROCHEMISTRY
ELECTRODES
ELEMENTS
HETEROCYCLIC COMPOUNDS
HOMOGENEOUS CATALYSIS
KINETICS
MATERIALS TESTING
NONMETALS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC POLYMERS
OXIDATION
OXYGEN
POLYMERS
POLYVINYLS
PYRIDINES
PYROLYTIC CARBON
REACTION KINETICS
REDOX POTENTIAL
TESTING
TRANSITION ELEMENT COMPLEXES
400201* -- Chemical & Physicochemical Properties
400400 -- Electrochemistry
AZINES
CARBON
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
COPPER COMPLEXES
ELECTROCATALYSTS
ELECTROCHEMISTRY
ELECTRODES
ELEMENTS
HETEROCYCLIC COMPOUNDS
HOMOGENEOUS CATALYSIS
KINETICS
MATERIALS TESTING
NONMETALS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC POLYMERS
OXIDATION
OXYGEN
POLYMERS
POLYVINYLS
PYRIDINES
PYROLYTIC CARBON
REACTION KINETICS
REDOX POTENTIAL
TESTING
TRANSITION ELEMENT COMPLEXES