Properties of CO sub 2 mixtures with N sub 2 and with CH sub 4. Topical report, June 1988

Technical Report · Wed Jun 01 04:00:00 EDT 1988

OSTI ID:6753949

Bailey, D M; Esper, G J; Holste, J C; Hall, K R; Eubank, P T

The project objective is to produce accurate, self consistent thermodynamic property data for mixtures of carbon dioxide with other natural and synthetic gas components. The thermodynamic properties include density, virial coefficients, energies (internal, Helmholtz, Gibbs), enthalpy, entropy, and phase equilibrium. The natural and synthetic gas components are methane, ethane, nitrogen, and hydrogen sulfide. The report includes Burnett and Burnett-isochoric data for two gravimetrically prepared, nominally equimolar mixtures of carbon dioxide with methane and with nitrogen. For each mixture the Burnett measurements are at 300 and 400 K (80 and 260F), and the Burnett-isochoric measurements are in the range 205 < T/K < 320 (-90 < t/F < 116) and 0.1 < P/MPa < 48(15 < P/psia < 7,000). Derived properties reported here include densities, second and third virial coefficients, interaction second virial coefficients, energies, enthalpies, and entropies. Portions of the VLE boundaries within the range of the measurements also are reported.

• Research Organization: Texas A and M Univ., College Station, TX (USA). Research Foundation
• OSTI ID: 6753949
• Report Number(s): PB-90-228156/XAB
• Country of Publication: United States
• Language: English

Related Subjects

03 NATURAL GAS
033000* -- Natural Gas-- Properties &amp; Composition
36 MATERIALS SCIENCE
360603 -- Materials-- Properties
ALKANES
CARBON COMPOUNDS
CARBON DIOXIDE
CARBON OXIDES
CHALCOGENIDES
DENSITY
DIAGRAMS
DISPERSIONS
DOCUMENT TYPES
ELEMENTS
ENERGY
ENTHALPY
ENTROPY
ETHANE
FREE ENERGY
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN SULFIDES
METHANE
MIXTURES
NITROGEN
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHASE DIAGRAMS
PHYSICAL PROPERTIES
PROGRESS REPORT
SULFIDES
SULFUR COMPOUNDS
THERMODYNAMIC PROPERTIES