Poisoning of resin supported catalyst
A method is described of enhancing performance of a combined hydroformylation/reduction reaction of an olefin liquid feed in the presence of a resin-supported transition metal complex catalyst. The method comprises: (a) preparing a resin-supported transition metal complex catalyst for use in a combined hydroformylation/reduction reaction substantially free of halides and halide salts in the metal complex catalyst; and (b) introducing an olefin liquid feed to the resin-supported catalyst for conducting a combined hydroformylation/reduction reaction, in the presence of CO and H/sub 2/. The olefin feed has a specified maximum limit of halide concentration sufficiently low to enable continued indefinite operation of the combined hydroformylation/reduction reaction process without halide poisoning.
- Assignee:
- Dow Chemical Co., Midland, MI
- Patent Number(s):
- US 4642395
- OSTI ID:
- 6730666
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
400201* -- Chemical & Physicochemical Properties
ALKENES
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBONYLATION
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
COMPLEXES
ELEMENTS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
HYDROGEN
NONMETALS
ORGANIC COMPOUNDS
ORGANIC POLYMERS
OXIDES
OXYGEN COMPOUNDS
PETROCHEMICALS
PETROLEUM PRODUCTS
POLYMERS
QUANTITY RATIO
REDUCTION
RESINS
TRANSITION ELEMENT COMPLEXES