Ghost vesicles

Journal Article · Sun Jan 01 04:00:00 EST 1984 · J. Am. Chem. Soc.; (United States)

DOI:https://doi.org/10.1021/ja00331a071· OSTI ID:6729775

Regen, S L; Shin, J S; Hainfeld, J F; Wall, J S

The synthesis and preliminary characterization of the first example of ghost vesicle derived from polymerized vesicles of diallylammonium dihexadecylphosphate (1) plus sodium dihexadecylphosphate (2) are described herein. Vesicle polymerization was carried out by direct uv irradiation, and thin-layer chromatography indicated the disappearance of 1, retention of 2, and a product remaining at the origin. The resulting polymer was collected and analyzed, and the analysis agreed quite well with the theoretical values. The ir spectrum of the polymer showed nearly complete disappearance of the olefinic absorption band nu/sub c = c/ at 1635 cm/sup -1/ indicating that the extent of polymerization was high. 12 references, 2 figures.

• Research Organization: Marquette Univ., Milwaukee, Wisconsin
• DOE Contract Number: AC02-77ER04446
• OSTI ID: 6729775
• Journal Information: J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 106; ISSN JACSA
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360601 -- Other Materials-- Preparation & Manufacture
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CHEMICAL PREPARATION
CHEMICAL REACTIONS
CROSS-LINKING
ELECTROMAGNETIC RADIATION
POLYMERIZATION
POLYMERS
RADIATIONS
SPHERES
SURFACTANTS
SYNTHESIS
ULTRAVIOLET RADIATION