Polymerization of oriented monomers. VI. Polymerization of monomeric Di(undecenyl) phosphate vesicles to stable polymeric vesicles

Journal Article · Wed Sep 01 04:00:00 EDT 1982 · J. Polym. Sci., Polym. Chem. Ed.; (United States)

DOI:https://doi.org/10.1002/pol.1982.170200916· OSTI ID:6862618

Paleos, C M ^[1]; Christias, C; Evangelatos, G P; Dais, P

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1. NRC ''Demokritos'', Aghia Paraskevi Attikis, Greece

The synthesis of a novel vesicle-forming surfactant monomer, i.e., of di(undecenyl) phosphate is reported. Vesicles formed from this monomer were irradiated by ..gamma.. rays for the production of polymeric vesicles. Polymerization was studied in conjunction with the model of the monomeric vesicles and the structure of the polymers was primarily studied with /sup 1/H-NMR spectra. It was further established that polymerized vesicles retain the structure of their monomeric counterparts while exhibiting higher stability than the unpolymerized vesicles.

• OSTI ID: 6862618
• Journal Information: J. Polym. Sci., Polym. Chem. Ed.; (United States), Journal Name: J. Polym. Sci., Polym. Chem. Ed.; (United States) Vol. 20:9; ISSN JPLCA
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTIONS
CHEMISTRY
ELECTROMAGNETIC RADIATION
GAMMA RADIATION
IONIZING RADIATIONS
MEMBRANES
MONOMERS
ORGANIC COMPOUNDS
ORGANIC POLYMERS
OXYGEN COMPOUNDS
PHOSPHATES
PHOSPHORUS COMPOUNDS
POLYMERIZATION
POLYMERS
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIATIONS
STABILITY
STRUCTURAL CHEMICAL ANALYSIS
SURFACTANTS
SYNTHESIS