Metal alkoxides: models for metal oxides. 2. Addition of ethyne, propyne, and 2-butyne to Mo/sub 2/(OR)/sub 6/ (M triple bond M) compounds (R = t-Bu, i-Pr, and Ne). Characterization of. mu. -alkyne and. mu. -C/sub 4/H/sub 4/ adducts and an evaluation of their role in alkyne oligomerization reactions
Journal Article
·
· J. Am. Chem. Soc.; (United States)
Rapid reactions of hydrocarbon solutions of Mo/sub 2/(OR)/sub 6/(M triple bond M) compounds where R=t-Bu, i-Pr, and CH/sub 2/CMe/sub 3/ with the alkynes C/sub 2/H/sub 2/, MeC/sub 2/H, and MeC/sub 2/Me are reported. The ..mu..-acetylene and ..mu..-C/sub 4/H/sub 4/ adducts formed with the reaction products in the presence of pyridine have been isolated and characterized. X-ray diffraction and NMR studies of the adducts are reported. (BLM)
- Research Organization:
- Indiana Univ., Bloomington
- OSTI ID:
- 6713484
- Journal Information:
- J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 104:16; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ADDUCTS
ALKYNES
AZINES
BOND LENGTHS
CHALCOGENIDES
CHEMICAL REACTIONS
COHERENT SCATTERING
DATA
DIFFRACTION
DIMENSIONS
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
INFORMATION
LENGTH
MAGNETIC RESONANCE
MOLYBDENUM COMPOUNDS
MOLYBDENUM OXIDES
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PYRIDINES
RESONANCE
SCATTERING
STRUCTURAL MODELS
TRANSITION ELEMENT COMPOUNDS
X-RAY DIFFRACTION
400201 -- Chemical & Physicochemical Properties
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ADDUCTS
ALKYNES
AZINES
BOND LENGTHS
CHALCOGENIDES
CHEMICAL REACTIONS
COHERENT SCATTERING
DATA
DIFFRACTION
DIMENSIONS
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
INFORMATION
LENGTH
MAGNETIC RESONANCE
MOLYBDENUM COMPOUNDS
MOLYBDENUM OXIDES
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PYRIDINES
RESONANCE
SCATTERING
STRUCTURAL MODELS
TRANSITION ELEMENT COMPOUNDS
X-RAY DIFFRACTION