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Title: Metal alkoxides: models for metal oxides. Part 4. Alkyne adducts of ditungsten hexaalkoxides and evidence for an equilibrium between dimetallatetrahedrane and methylidynemetal complexes: W/sub 2/(. mu. -C/sub 2/H/sub 2/)in equilibrium2W identical with CH

Journal Article · · J. Am. Chem. Soc.; (United States)
DOI:https://doi.org/10.1021/ja00334a055· OSTI ID:6102970
; ; ;

The preparation and characterization of alkyne adducts of hexaalkoxides of ditungsten are discussed. Solid state structure, bonding considerations, /sup 1/H NMR studies, and /sup 13/C NMR studies are all discussed. Evidence for identification of the W identical with CH group and for the equilibrium between the dimetallatetrahedrane and the methylidynemetal complex are presented.

Research Organization:
Indiana Univ., Bloomington
OSTI ID:
6102970
Journal Information:
J. Am. Chem. Soc.; (United States), Vol. 106:22
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
TUNGSTEN COMPLEXES
CHEMICAL PREPARATION
CRYSTAL STRUCTURE
ALKYNES
CARBON 13
EXPERIMENTAL DATA
NMR SPECTRA
PROTONS
BARYONS
CARBON ISOTOPES
COMPLEXES
DATA
ELEMENTARY PARTICLES
EVEN-ODD NUCLEI
FERMIONS
HADRONS
HYDROCARBONS
INFORMATION
ISOTOPES
LIGHT NUCLEI
NUCLEI
NUCLEONS
NUMERICAL DATA
ORGANIC COMPOUNDS
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
400201 - Chemical & Physicochemical Properties