Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Low-temperature synthesis of ZrW{sub 2}O{sub 8} and Mo-substituted ZrW{sub 2}O{sub 8}

Journal Article · · Journal of Solid State Chemistry
;  [1];  [2]
  1. Oregon State Univ., Corvallis, OR (United States)
  2. Wah Chang, Albany, OR (United States)

A low-temperature synthesis of ZrW{sub 2}O{sub 8} and HfW{sub 2}O{sub 8} has been developed which yields the normal crystalline forms of these compounds at a temperature where they are presumably not thermodynamically stable. This same synthesis approach has allowed for the first time the synthesis of cubic ZrW{sub 2{minus}x}Mo{sub x}O{sub 8} phases up to x = 1.5.

OSTI ID:
669780
Journal Information:
Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Journal Issue: 2 Vol. 139; ISSN 0022-4596; ISSN JSSCBI
Country of Publication:
United States
Language:
English

Similar Records

Phase transition behavior for ZrW{sub 2-x}Mo{sub x}O{sub 8} compositions at elevated temperatures
Journal Article · Sat Aug 15 00:00:00 EDT 2009 · Journal of Solid State Chemistry · OSTI ID:21370516

Negative thermal expansion in ZrW{sub 2}O{sub 8} and HfW{sub 2}O{sub 8}
Journal Article · Sat Nov 30 23:00:00 EST 1996 · Chemistry of Materials · OSTI ID:518368

Isotropic negative thermal expansion in ZrW 2 O 8 and HfW 2 O 8 from 1100 to 1275°C
Journal Article · Tue Feb 06 23:00:00 EST 2024 · Journal of the American Ceramic Society · OSTI ID:2582717