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Unified analysis of multipole and finite-mass corrections in long-range Coulombic interactions

Journal Article · · Phys. Rev. A; (United States)
Simple expressions are derived for all multipole, nonadiabatic, and finite-nuclear-mass corrections to the long-range effective potential due to two--Coulomb-photon exchange at threshold energy and also first order in energy correction for the scattering between a spinless point charged particle and a spinless Coulombic complex and between two spinless Coulombic complexes. All these corrections are treated on equal footing and the results are expressed, respectively, in terms of single-center and London-analog two-center atomic multipole spectral sums. An isomorphism between the point-particle--complex interaction and the complex-complex interaction is derived. All Hughes-Eckert--type mass-polarization terms are avoided by suitable choice of Jacobi coordinates.
Research Organization:
Institute for Theoretical Physics, University of California, Santa Barbara, California 93106
OSTI ID:
6642296
Journal Information:
Phys. Rev. A; (United States), Journal Name: Phys. Rev. A; (United States) Vol. 38:11; ISSN PLRAA
Country of Publication:
United States
Language:
English