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Title: Crystal structure of (4-aminopyridine)bis-1, 10-phenanthroline copper(II) hexaflourophosphate acetone adduct, [Cu(C[sub 5]H[sub 6]N[sub 2])(C[sub 12]H[sub 8]N[sub 2])[sub 2]](PF[sub 6])[sub 2] [sm bullet] C[sub 3]H[sub 6]O

Journal Article · · Journal of Crystallographic and Spectroscopic Research; (United States)
DOI:https://doi.org/10.1007/BF01190054· OSTI ID:6623808
;  [1]; ; ;  [2];  [3]
  1. Rhodes College, Memphis, TN (United States)
  2. Christian Brothers Univ., Memphis, TN (United States)
  3. Univ. of Arkansas, Faryetteville (United States)
+ Show Author Affiliations

Numerous examples of five coordination of Cu(II) are known and have been reviewed by O'Brien (1984) and Hathaway (1982, 1983). The ability of the bis (1, 10-phenanthroline) copper (II) cation to add an additional ligand to make a five coordinate species is well documented. Structures previously reported for Cu(phen)[sub 2] X cations include complexes in which X is a small molecule or ion such as Cl- (Boys et al., 1981), CN- (Anderson, 1975) and H[sub 2]O (Nakai et al., 1975; Nakai et al., 1978) and, more recently, a large heterocycle such as 3,5-dimethyl-pyridine (Jeter et al., 1988). With a small ligand near trigonal bipyramidal geometry seems to prevail, but, with the large heterocylic ligand the geometry approximately a square pyramid. In this work, we report the structure of a second complex with a large heterocylic ligand, 4-aminopyridine.

OSTI ID:
6623808
Journal Information:
Journal of Crystallographic and Spectroscopic Research; (United States), Vol. 23:3; ISSN 0277-8068
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
COPPER COMPLEXES
COORDINATION NUMBER
CRYSTAL STRUCTURE
ACETONE
ADDUCTS
COMPLEXES
LIGANDS
PHENANTHROLINES
PHOSPHATES
PYRIDINES
AROMATICS
AZAARENES
AZINES
HETEROCYCLIC COMPOUNDS
KETONES
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PHOSPHORUS COMPOUNDS
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties