Tris(phenyl(difluorophosphino)amino)phosphine (P(N(C/sub 6/H/sub 5/)PF/sub 2/)/sub 3/), a novel tridentate strong. pi. -acceptor ligand forming cage chelates. Crystal structure of the chelate complex P(N(C/sub 6/H/sub 5/)PF/sub 2/)/sub 3/MO(CO)/sub 3/
Journal Article
·
· J. Am. Chem. Soc.; (United States)
- Oak Ridge National Lab., TN
The space group of P(N(C/sub 6/H/sub 5/)PF/sub 2/)/sub 3/ Mo(CO)/sub 3/ is P2/sub 1//c. The unit cell parameters are a = 8.683(1) A, b = 28.218(7) A, c = 15.338 (2) A, and ..beta.. = 118.12 (1)/sup 0/. The structure is that of an octahedral fac-L/sub 3/ Mo(CO)/sub 3/ complex. The ligand has its PF/sub 2/ groups linked to the Mo atom. (DLC)
- DOE Contract Number:
- W-7405-ENG-26
- OSTI ID:
- 6243823
- Journal Information:
- J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 103:17; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Metal complexes of fluorophosphines. 13. Reaction of fac-(CH/sub 3/CN)/sub 3/Mo(CO)/sub 3/ with (methylamino)bis(difluorophosphine). X-ray crystal structure analysis of a novel binuclear molybdenum fluorophosphine carbonyl complex with a bridging chlorine atom: (CO)/sub 2/Mo(/sup +/-CH/sub 3/N(PF/sub 2/)/sub 2/)/sub 2/(. mu. -PF/sub 2/)(. mu. -Cl)Mo(CO)(PF/sub 2/NHCH/sub 3/)
NaBH/sub 4/ reduction of CO in the cationic iron carbonyl complexes (C/sub 5/Me/sub 5/Fe(CO)/sub 2/L)/sup +/PF/sub 6//sup /minus// (L = CO or phosphine)
Structure of ((eta-C/sub 5/H/sub 5/)Fe(CO)/sub 2/(CS))PF/sub 6/, a comparison of M-CS and M-CO bonding
Journal Article
·
Sat Dec 31 23:00:00 EST 1983
· Inorg. Chem.; (United States)
·
OSTI ID:5897113
NaBH/sub 4/ reduction of CO in the cationic iron carbonyl complexes (C/sub 5/Me/sub 5/Fe(CO)/sub 2/L)/sup +/PF/sub 6//sup /minus// (L = CO or phosphine)
Journal Article
·
Mon Aug 01 00:00:00 EDT 1988
· Organometallics; (United States)
·
OSTI ID:5885541
Structure of ((eta-C/sub 5/H/sub 5/)Fe(CO)/sub 2/(CS))PF/sub 6/, a comparison of M-CS and M-CO bonding
Journal Article
·
Tue Feb 10 23:00:00 EST 1987
· Inorg. Chem.; (United States)
·
OSTI ID:7043601
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CHELATING AGENTS
COHERENT SCATTERING
COMPLEXES
CRYSTAL STRUCTURE
CRYSTALS
DATA
DIFFRACTION
EXPERIMENTAL DATA
INFORMATION
LIGANDS
MOLYBDENUM COMPLEXES
MONOCRYSTALS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PHOSPHINES
PHOSPHORUS COMPOUNDS
SCATTERING
TRANSITION ELEMENT COMPLEXES
X-RAY DIFFRACTION
400201* -- Chemical & Physicochemical Properties
CHELATING AGENTS
COHERENT SCATTERING
COMPLEXES
CRYSTAL STRUCTURE
CRYSTALS
DATA
DIFFRACTION
EXPERIMENTAL DATA
INFORMATION
LIGANDS
MOLYBDENUM COMPLEXES
MONOCRYSTALS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PHOSPHINES
PHOSPHORUS COMPOUNDS
SCATTERING
TRANSITION ELEMENT COMPLEXES
X-RAY DIFFRACTION