Quinoline hydrodenitrogenation: reaction network and kinetics

Conference · Mon Aug 01 00:00:00 EDT 1977 · Prepr., Div. Pet. Chem., Am. Chem. Soc.; (United States)

OSTI ID:6606908

Shih, S S; Katzer, J R; Kwart, H; Stiles, A B

In this study, the reaction network and reaction kinetics for quinoline HDN were quantitatively determined. The effects of presulfiding, of H/sub 2/S presence during reaction, and of reaction temperature and pressure on the reaction kinetics have been studied. The HDN kinetics were investigated under high-pressure, liquid-phase conditions which were as closely relevant to practical industrial conditions as possible. The objectives of this work were to quantify the reaction kinetics and reaction network for the model compound studied in order to gain some quantitative insight into the chemistry of the catalytic action.

• Research Organization: Univ. of Delaware, Newark
• OSTI ID: 6606908
• Report Number(s): CONF-770301-P3
• Journal Information: Prepr., Div. Pet. Chem., Am. Chem. Soc.; (United States), Journal Name: Prepr., Div. Pet. Chem., Am. Chem. Soc.; (United States) Vol. 22:3; ISSN ACPCA
• Country of Publication: United States
• Language: English

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BITUMENS
CATALYSIS
CHALCOGENIDES
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COAL LIQUIDS
DENITRIFICATION
ELEMENTS
ENERGY SOURCES
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KINETICS
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NONMETALS
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ORGANIC COMPOUNDS
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PETROLEUM
PRESSURE DEPENDENCE
PYRIDINES
QUINOLINES
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SYNTHETIC FUELS
SYNTHETIC PETROLEUM
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