Pulse radiolysis experiment on solute deuteration effects on the electron transfer rate in organic glasses at 77 K

Journal Article · Thu May 13 04:00:00 EDT 1982 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100207a026· OSTI ID:6592234

Kira, A ^[1]; Nosaka, Y; Imamura, M; Ichikawa, T

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1. The Inst. of Physical and Chemical Research, Saitama, Japan

Rates of electron transfers from trapped electrons to deuterated and protiated solute molecules were comparatively measured in 2-methyltetrahydrofuran glass at 77 K by the pulse radiolysis method. Similar measurement was done for electron transfers from solute molecules to trapped holes in sec-butyl chloride at 77 K. The compounds used were biphenyl, naphthalene, pyrene, acridine, nitrobenzene, and p-benzoquinone. The magnitude of deuteration effects on the rate did not exceed the experimental errors.

• OSTI ID: 6592234
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 86:10; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400302 -- Organic Chemistry-- Isotope Effects-- (-1987)
400600* -- Radiation Chemistry
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTIONS
CHEMISTRY
DECAY
DECOMPOSITION
DEUTERATION
DEUTERIUM
ELECTRON TRANSFER
ELECTRONS
ELEMENTARY PARTICLES
EQUATIONS
FERMIONS
FRANCK-CONDON PRINCIPLE
FURANS
HETEROCYCLIC COMPOUNDS
HYDROGEN ISOTOPES
ISOTOPE EFFECTS
ISOTOPES
KINETICS
LEPTONS
LIGHT NUCLEI
LOW TEMPERATURE
MTHF
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIOLYSIS
STABLE ISOTOPES
SURVIVAL CURVES
TETRAHYDROFURAN
TRAPPED ELECTRONS