Positive-charge transfer in irradiated sec-butyl chloride glassy solutions at 77 K as studied by the pulse radiolysis method

Journal Article · Thu Aug 23 04:00:00 EDT 1979 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100480a019· OSTI ID:5711362

Nosaka, Y; Kira, A; Imamura, M

The time evolution of optical absorptions of cationic species in sec-butyl chloride glasses at 77 K was observed over the range of 10/sup -5/ to 1 s after irradiation with electron pulses. A band tail newly found at wavelengths shorter than 420 nm in a pure glass is assignable to a precursor of the trapped hole characterized by the 480-nm band. In the presence of an aromatic solute, trapped holes decay over the above time range and solute cations grow concurrently. In biphenyl-pyrene solutions, the decay of biphenyl cations is accompanied by the growth of pyrene cations. The observed positive-charge transfer is consistent with long-range electron transfer. 6 figures.

• Research Organization: Inst. of Physical and Chemical Research, Wako-Shi, Japan
• OSTI ID: 5711362
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 83:17; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
ABSORPTION SPECTRA
AROMATICS
BIPHENYL
CATIONS
CHARGED PARTICLES
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISTRY
CHLORINATED ALIPHATIC HYDROCARBONS
CONDENSED AROMATICS
DATA
DATA FORMS
DECOMPOSITION
ELECTRON TRANSFER
EXPERIMENTAL DATA
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
INFORMATION
IONS
IRRADIATION
ISOLATED VALUES
LOW TEMPERATURE
NUMERICAL DATA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PRECURSOR
PULSED IRRADIATION
PYRENE
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIOLYSIS
SPECTRA
TEMPERATURE DEPENDENCE
TIME DEPENDENCE
YIELDS