An investigation of composite electrolytes by mixing polyethylene oxide- and polytetramethylene glycol-based waterborne polyurethane with the addition of LiClO{sub 4}/propylene carbonate
- National Cheng Kung Univ., Tainan (Taiwan, Province of China). Dept. of Chemical Engineering
Various composite electrolytes (CE) were prepared by mixing polytetramethylene glycol-based waterborne polyurethane [WPU(PTMG)], polyethylene oxide (PEO), and LiClO{sub 4}/propylene carbonate (PC). The conductivity of these CEs was investigated using ac impedance. Differential scanning calorimetry (DSC) and polarizing microscopy (PM) were employed for material characterization. The temperature dependence of the conductivity follows the Arrhenius law for samples with a LiClO{sub 4}/PC content larger than 30%, while for samples with LiClO{sub 4}/PC content approximating 8%, it shows linear segments separated by a transition zone between 25 and 65 C. According to the ac and DSC results, the conductivity is increased, and the melting temperature is decreased by increasing the LiClO{sub 4}/PC content. PM results indicate that the increase in PEO ratio increases the crystallinity of the PEO-WPU(PTMG) films. When LiClO{sub 4}/PC is added, the increase in PEO ratio results in an increase in conductivity. The CE comprising 33% PEO, 17% WPU(PTMG), and 50% LiClO{sub 4}/PC exhibits conductivities as high as Ca. {approximately}10{sup {minus}2} S/cm at 85 C and 5 {times} 10{sup {minus}3} S/cm at 15 C.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 659176
- Journal Information:
- Journal of the Electrochemical Society, Vol. 145, Issue 10; Other Information: PBD: Oct 1998
- Country of Publication:
- United States
- Language:
- English
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