Hydrazine carboxylate precursors to fine particle titania, zirconia and zirconium titanate

Journal Article · Sat May 01 04:00:00 EDT 1993 · Materials Research Bulletin; (United States)

DOI:https://doi.org/10.1016/0025-5408(93)90131-V· OSTI ID:6582367

Sekar, M M.A.; Patil, K C ^[1]

---

1. Indian Inst. of Science, Bangalore (India)

Titanyl hydrazine carboxylate dihydrate, TiO(N[sub 2]H[sub 3]COO)[sub 2] [center dot] 2H[sub 2]O, zirconyl hyrazine and carboxylate, dihydrate, ZrO(N[sub 2]H[sub 3]COO)[sub 2] [center dot] 2H[sub 2]O and their solid solution, ZrTiO[sub 2] (N[sub 2]H[sub 3]COO)[sub 4] [center dot] 4H[sub 2]O have been prepared for the first time and investigated as precursors to fine particle TiO[sub 2], ZrO[sub 2] and ZrTiO[sub 4] respectively. Titania(anatase) formed has a very high surface area of 110 m[sup 10]/g and zirconium titanate showed very low dielectric loss (4 x 10[sup [minus]]).

• OSTI ID: 6582367
• Journal Information: Materials Research Bulletin; (United States), Journal Name: Materials Research Bulletin; (United States) Vol. 28:5; ISSN MRBUAC; ISSN 0025-5408
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360201* -- Ceramics
Cermets
& Refractories-- Preparation & Fabrication
CHALCOGENIDES
CHEMICAL REACTIONS
DECOMPOSITION
DISPERSIONS
HYDRAZINE
MIXTURES
NITROGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PRECURSOR
SOLID SOLUTIONS
SOLUTIONS
SYNTHESIS
TITANATES
TITANIUM COMPOUNDS
TITANIUM OXIDES
TRANSITION ELEMENT COMPOUNDS
ZIRCONIUM COMPOUNDS
ZIRCONIUM OXIDES