Diosmacycloalkanes as models for the formation of hydrocarbons from surface methylenes

Technical Report · Sat May 01 04:00:00 EDT 1993

DOI:https://doi.org/10.2172/6581010· OSTI ID:6581010

Norton, J R

The report is divided into: vibrational models for surface ethylidenes (on catalyst surfaces); alpha vs beta hydrogen elimination in formation of propene from an osmacyclobutane; mechanism of formation and fragmentation of diosmacyclobutanes; reaction of dienes and allenes with diosmacyclobutanes; structure of Os(CO)[sub 4](C[sub 2]H[sub 4]), an osmacyclopropane; and reaction of [mu]-oxobis [(trifluoromethanesulfanato) (phenyl)iodine(III)] with Group 14 propargyl derivatives and a propargyl ether. 16 refs, figs.

• Research Organization: Colorado State Univ., Fort Collins, CO (United States)
• Sponsoring Organization: DOE; USDOE, Washington, DC (United States)
• DOE Contract Number: FG02-84ER13299
• OSTI ID: 6581010
• Report Number(s): DOE/ER/13299-9; ON: DE93013382
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKANES
ALKENES
ALLENE
CARBONYLS
CATALYSTS
CHEMICAL REACTIONS
COMPLEXES
CYCLOALKANES
DEUTERIUM COMPOUNDS
DIENES
DOCUMENT TYPES
HYDROCARBONS
HYDROGEN COMPOUNDS
INFRARED SPECTRA
ORGANIC COMPOUNDS
OSMIUM COMPLEXES
POLYENES
PROGRESS REPORT
PROPYLENE
RADICALS
SPECTRA
SURFACES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES