Diosmacycloalkanes as models for the formation of hydrocarbons from surface methylenes. Progress report, November 1, 1992--October 31, 1993
The report is divided into: vibrational models for surface ethylidenes (on catalyst surfaces); alpha vs beta hydrogen elimination in formation of propene from an osmacyclobutane; mechanism of formation and fragmentation of diosmacyclobutanes; reaction of dienes and allenes with diosmacyclobutanes; structure of Os(CO){sub 4}(C{sub 2}H{sub 4}), an osmacyclopropane; and reaction of {mu}-oxobis [(trifluoromethanesulfanato) (phenyl)iodine(III)] with Group 14 propargyl derivatives and a propargyl ether. 16 refs, figs.
- Research Organization:
- Colorado State Univ., Fort Collins, CO (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG02-84ER13299
- OSTI ID:
- 10149263
- Report Number(s):
- DOE/ER/13299--9; ON: DE93013382
- Country of Publication:
- United States
- Language:
- English
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