The Jahn-Teller effect in the lowest charge transfer state of UF/sub 6/. Technical report
Technical Report
·
OSTI ID:6579182
The neat and mixed crystal emission spectra of UF/sub 6/ are analyzed. The data are interpreted as being indicative of a substantial molecular Jahn-Teller interaction in the excited charge transfer state. By use of a modified Franck-Condon analysis for a 3-dimensional vibrational space, it is found that D(5) is approx. 2.02 and that the excited state is distorted along each of three v5 coordinates by roughly 0.09 A.
- Research Organization:
- Colorado State Univ., Fort Collins (USA). Dept. of Chemistry
- OSTI ID:
- 6579182
- Report Number(s):
- AD-A-053855
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
36 MATERIALS SCIENCE
360603 -- Materials-- Properties
640302* -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACTINIDE COMPOUNDS
EMISSION SPECTRA
ENERGY LEVELS
EXCITED STATES
FLUORIDES
FLUORINE COMPOUNDS
FRANCK-CONDON PRINCIPLE
HALIDES
HALOGEN COMPOUNDS
JAHN-TELLER EFFECT
SPECTRA
URANIUM COMPOUNDS
URANIUM FLUORIDES
URANIUM HEXAFLUORIDE
VIBRATIONAL STATES
360603 -- Materials-- Properties
640302* -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACTINIDE COMPOUNDS
EMISSION SPECTRA
ENERGY LEVELS
EXCITED STATES
FLUORIDES
FLUORINE COMPOUNDS
FRANCK-CONDON PRINCIPLE
HALIDES
HALOGEN COMPOUNDS
JAHN-TELLER EFFECT
SPECTRA
URANIUM COMPOUNDS
URANIUM FLUORIDES
URANIUM HEXAFLUORIDE
VIBRATIONAL STATES