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Renner-Teller, Jahn-Teller and Herzberg-Teller effects for geminal charge transfer in high T{sub c} superconductivity

Conference ·
OSTI ID:456940
 [1]
  1. Catholic Univ. of America, Washington, DC (United States)

Instead of the Cooper pair of BCS theory, the authors incorporate the chemical structural effects of pairwise movement by using geminals (two-electron wavefunctions), rather than the simple orbital (one-electron wavefunction) model. Instead of the nearest-neighbor antisymmetric-type vibronic interaction of Bipolaron Theory, the authors emphasize the distant neighbor`s opposing vibrations in doped systems. Besides the Jahn-Teller effect of second-order energy, the authors propose Renner-Teller effect for crystals other than linear molecules, and obtain first-order energy of degenerate vibronic geminal states by using the Herzberg-Teller expansions of vibronic states of the Hamiltonian.

OSTI ID:
456940
Report Number(s):
CONF-9506113--
Country of Publication:
United States
Language:
English

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