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Adiabatic theory for the bipolaron

Journal Article · · Physical Review, B: Condensed Matter; (United States)
 [1]
  1. Institute of Mathematical Problems of Biology, Russian Academy of Sciences, Pushchino Moscow Region, 142292 (Russian Federation)

A translation-invariant adiabatic theory is constructed for the bipolaron. It is shown that motions in the bipolaron are divided: the relative electron coordinates describe fast electron oscillations in the induced polarization well and the center of mass coordinates represent slow electron movement followed by polarization. Nonlinear differential bipolaron equations are derived which are asymptotically exact in the adiabatic limit. Particlelike solutions of these equations correspond to the bipolaron bound state. The exact solution yields the value of the ion critical parameter [eta]=0.31 for which the bipolaron state is stable, where [eta]=[epsilon][sub [infinity]]/[epsilon][sub 0] and [epsilon][sub [infinity]],[epsilon][sub 0] are high-frequency and static dielectric permittivities. The energy, the total energy, the effective mass, the radius, and the critical values of the electron-phonon coupling constants are calculated for the bipolaron. The results obtained are generalized to the case of two-dimensional bipolarons.

OSTI ID:
6575789
Journal Information:
Physical Review, B: Condensed Matter; (United States), Journal Name: Physical Review, B: Condensed Matter; (United States) Vol. 51:6; ISSN PRBMDO; ISSN 0163-1829
Country of Publication:
United States
Language:
English

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