Conformational effects in alkoxy radicals

Journal Article · Sun Mar 01 04:00:00 EST 1981 · J. Chem. Phys.; (United States)

DOI:https://doi.org/10.1063/1.441434· OSTI ID:6572542

Box, H C; Freund, H G; Budzinski, E E

An alkoxy radical was identified in single crystals of cytidine-3'- monophosphate x irradiated at 4.2 /sup 0/K. Proton hyperfine couplings associated with the alkoxy radical absorption were determined from ENDOR measurements. The magnitudes of ..beta.. as well as ..gamma.. proton couplings are dependent upon the conformation of the radical. The conformation of alkoxy radicals is analyzed in terms of two dihedral angles and related to observed coupling tensors.

• Research Organization: Roswell Park Memorial Institute, Buffalo, NY
• OSTI ID: 6572542
• Journal Information: J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 74:5; ISSN JCPSA
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
ALKOXY RADICALS
AZINES
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTIONS
CHEMISTRY
CYTIDINE
DECOMPOSITION
ELECTROMAGNETIC RADIATION
ENDOR
HETEROCYCLIC COMPOUNDS
HYPERFINE STRUCTURE
IONIZING RADIATIONS
MAGNETIC RESONANCE
MOLECULAR STRUCTURE
NUCLEOSIDES
NUCLEOTIDES
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PHOSPHATES
PHOSPHORUS COMPOUNDS
PYRIMIDINES
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIATIONS
RADICALS
RADIOLYSIS
RESONANCE
RIBOSIDES
ULTRALOW TEMPERATURE
X RADIATION