Alkoxy radicals: Delta proton hyperfine couplings

Journal Article · Sun Apr 14 23:00:00 EST 1985 · J. Chem. Phys.; (United States)

DOI:https://doi.org/10.1063/1.448928· OSTI ID:5812423

Budzinski, E E; Box, H C

Single crystals of rhamnose were x irradiated at 4.2 K and the ESR and ENDOR spectra taken at 1.6 K. A component of the ESR absorption arises from an alkoxy radical exhibiting an unusual delta proton hyperfine coupling. Parallels between the radiation-induced oxidation of certain carbohydrates and that of amino acids are pointed out.

• Research Organization: Biophysics Department, Roswell Park Memorial Institute, Buffalo, New York 14263
• OSTI ID: 5812423
• Journal Information: J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 82:8; ISSN JCPSA
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
ALKOXY RADICALS
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTIONS
CHEMISTRY
CRYSTALS
DECOMPOSITION
ELECTROMAGNETIC RADIATION
ELECTRON SPIN RESONANCE
ENDOR
HYDROXY COMPOUNDS
HYPERFINE STRUCTURE
IONIZING RADIATIONS
MAGNETIC RESONANCE
MONOCRYSTALS
ORGANIC COMPOUNDS
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIATIONS
RADICALS
RADIOLYSIS
RESONANCE
ULTRALOW TEMPERATURE
X RADIATION