Infrared absorption spectroscopy and chemical kinetics of free radicals. [HCCN; CCH-H[sub 2] reaction; propargyl radical recombination]

Technical Report · Wed Mar 31 19:00:00 EST 1993

DOI:https://doi.org/10.2172/6566601· OSTI ID:6566601

Curl, R F; Glass, G P

During the last year, three projects were completed: a high resolution spectroscopic study of CH stretch of HCCN, measurement of rate constant of reaction between ethynyl (CCH) and H[sub 2] at 295-- 875 K, and measurement of recombination rate of propargyl (CH[sub 2]CCH) at room temperature. (DLC)

• Research Organization: Rice Univ., Houston, TX (United States)
• Sponsoring Organization: DOE; USDOE, Washington, DC (United States)
• DOE Contract Number: FG05-85ER13439
• OSTI ID: 6566601
• Report Number(s): DOE/ER/13439-8; ON: DE93015078
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
CARBON COMPOUNDS
CHEMICAL BONDS
CHEMICAL REACTIONS
DOCUMENT TYPES
ELEMENTS
ENERGY LEVELS
EXCITED STATES
HYDROGEN
INFRARED SPECTRA
NITROGEN COMPOUNDS
NONMETALS
PHOTOCHEMICAL REACTIONS
PROGRESS REPORT
RADICALS
SPECTRA
VIBRATIONAL STATES