Infrared absorption spectroscopy and chemical kinetics of free radicals
Conference
·
OSTI ID:139864
- Rice Univ., Houston, TX (United States)
This research is directed at the detection, monitoring, and study of chemical kinetic behavior by infrared absorption spectroscopy of small free radical species thought to be important intermediates in combustion. During the last year, infrared kinetic spectroscopy using excimer laser flash photolysis and color-center laser probing has been employed to study the high resolution spectrum of HCCN, the rate constant of the reaction between ethynyl (C{sub 2}H) radical and H{sub 2} in the temperature region between 295 and 875 K, and the recombination rate of propargyl (CH{sub 2}CCH) at room temperature.
- Research Organization:
- Brookhaven National Lab., Upton, NY (United States)
- OSTI ID:
- 139864
- Report Number(s):
- BNL--48923; CONF-9306172--; ON: DE93015758
- Resource Relation:
- 15. combustion research contractors` meeting, Lake Harmony, PA (United States), 2-4 Jun 1993; Is Part Of Fifteenth combustion research conference; PB: 391 p.
- Country of Publication:
- United States
- Language:
- English
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