Evidence for adduct formation at the semiconductor-solution interface. Photoluminescent properties of cadmium selenide in the presence of lanthanide. beta. -diketonate complexes

Journal Article · Thu Apr 05 04:00:00 EDT 1990 · Journal of Physical Chemistry; (USA)

DOI:https://doi.org/10.1021/j100370a062· OSTI ID:6551178

Murphy, C J; Ellis, A B ^[1]

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1. Univ. of Wisconsin, Madison (USA)

Photoluminescence (PL) measurements of etched, single-crystal n-CdSe demonstrate that the semiconductor surface engages in adduct formation with a family of lanthanide {beta}-diketonate complexes, Ln(fod){sub 3} (Ln = lanthanide; fod = 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato anion), in isooctane ambient.

• OSTI ID: 6551178
• Journal Information: Journal of Physical Chemistry; (USA), Journal Name: Journal of Physical Chemistry; (USA) Vol. 94:7; ISSN JPCHA; ISSN 0022-3654
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360603* -- Materials-- Properties
CADMIUM COMPOUNDS
CADMIUM SELENIDES
CHALCOGENIDES
DATA
DATA ANALYSIS
DYSPROSIUM
ELEMENTS
ERBIUM
EUROPIUM
EXPERIMENTAL DATA
GADOLINIUM
HOLMIUM
INFORMATION
LUMINESCENCE
MATERIALS
MEASURING INSTRUMENTS
MEASURING METHODS
METALS
NEODYMIUM
NUMERICAL DATA
PHOTOLUMINESCENCE
PRASEODYMIUM
RARE EARTHS
SELENIDES
SELENIUM COMPOUNDS
SEMICONDUCTOR MATERIALS
YTTERBIUM