Conductance and ion association in dimethylsulfite

Journal Article · Fri Aug 01 00:00:00 EDT 1986 · J. Solution Chem.; (United States)

DOI:https://doi.org/10.1007/BF00644598· OSTI ID:6496380

Plichta, E; Salomon, M; Slane, S; Uchiyama, M

The electrolytic conductances of LiClO/sub 4/, LiAsF/sub 6/, NaClO/sub 4/ and the n-butylammonium salts Bu/sub 4/NCl, Bu/sub 4/NClO/sub 4/, and Bu/sub 4/NBPh/sub 4/ (tetraphenylborate) have been determined in dimethylsulfite at 25/sup 0/C. Ion association constants calculated from these data are interpreted in terms of solvent-separated ion pairs (for LiClO/sub 4/, LiAsF/sub 6/, and NaClO/sub 4/), and contact ion pairs (for the n-butyl-ammonium salts). Comparisons are made for analogous electrolytes in acetone, and in which all salts form contact ion pairs.

• Research Organization: Army Electronics Technology and Devices Lab., Fort Monmouth, NJ
• OSTI ID: 6496380
• Journal Information: J. Solution Chem.; (United States), Journal Name: J. Solution Chem.; (United States) Vol. 15:8; ISSN JSLCA
• Country of Publication: United States
• Language: English

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