Conductance of 1:1 electrolytes in methyl formate
Journal Article
·
· J. Solution Chem.; (United States)
The electrolytic conductivities of LiClO/sub 4/, LiAlCl/sub 4/, LiAsF/sub 6/, NaClO/sub 4/, NaBPh/sub 4/, and Bu/sub 4/NClO/sub 4/ have been measured in methyl formate at 25/sup 0/C. Evidence is presented for strong association between the perchlorate ion and the formyl proton of the solvent. Ion association and triple ion formation constants suggest that LiClO/sub 4/, LiAlCl/sub 4/, and NaClO/sub 4/ form solvent separate ion pairs and triple ions. NaBPh/sub 4/ forms contact ion pairs and triple ions, and the remaining salts appear to form both types of ion pairs and triple ions.
- Research Organization:
- Army ET and DL, Fort Monmouth, NJ
- OSTI ID:
- 5930610
- Journal Information:
- J. Solution Chem.; (United States), Journal Name: J. Solution Chem.; (United States) Vol. 16:3; ISSN JSLCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
30 DIRECT ENERGY CONVERSION
300503* -- Fuel Cells-- Materials
Components
& Auxiliaries
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400400 -- Electrochemistry
ALKALI METAL COMPOUNDS
ALUMINIUM CHLORIDES
ALUMINIUM COMPOUNDS
ARSENIC COMPOUNDS
ARSENIC FLUORIDES
CARBOXYLIC ACID SALTS
CHLORIDES
CHLORINE COMPOUNDS
COMPILED DATA
CURRENT DENSITY
DATA
DIRECT ENERGY CONVERTERS
EFFICIENCY
ELECTRIC CONDUCTIVITY
ELECTRIC DISCHARGES
ELECTRICAL PROPERTIES
ELECTROCHEMICAL CELLS
ELECTROLYTES
ENERGY EFFICIENCY
FLUORIDES
FLUORINE COMPOUNDS
FORMATE FUEL CELLS
FORMATES
FUEL CELLS
HALIDES
HALOGEN COMPOUNDS
INFORMATION
LITHIUM CHLORIDES
LITHIUM COMPOUNDS
LITHIUM FLUORIDES
LITHIUM HALIDES
LITHIUM PERCHLORATES
MATERIALS TESTING
NUMERICAL DATA
ORGANIC BORON COMPOUNDS
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
PERCHLORATES
PHYSICAL PROPERTIES
SODIUM COMPOUNDS
SODIUM PERCHLORATES
SOLVATION
SOLVENT PROPERTIES
TESTING
TRANSITION ELEMENT COMPOUNDS
VANADATES
VANADIUM COMPOUNDS
300503* -- Fuel Cells-- Materials
Components
& Auxiliaries
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400400 -- Electrochemistry
ALKALI METAL COMPOUNDS
ALUMINIUM CHLORIDES
ALUMINIUM COMPOUNDS
ARSENIC COMPOUNDS
ARSENIC FLUORIDES
CARBOXYLIC ACID SALTS
CHLORIDES
CHLORINE COMPOUNDS
COMPILED DATA
CURRENT DENSITY
DATA
DIRECT ENERGY CONVERTERS
EFFICIENCY
ELECTRIC CONDUCTIVITY
ELECTRIC DISCHARGES
ELECTRICAL PROPERTIES
ELECTROCHEMICAL CELLS
ELECTROLYTES
ENERGY EFFICIENCY
FLUORIDES
FLUORINE COMPOUNDS
FORMATE FUEL CELLS
FORMATES
FUEL CELLS
HALIDES
HALOGEN COMPOUNDS
INFORMATION
LITHIUM CHLORIDES
LITHIUM COMPOUNDS
LITHIUM FLUORIDES
LITHIUM HALIDES
LITHIUM PERCHLORATES
MATERIALS TESTING
NUMERICAL DATA
ORGANIC BORON COMPOUNDS
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
PERCHLORATES
PHYSICAL PROPERTIES
SODIUM COMPOUNDS
SODIUM PERCHLORATES
SOLVATION
SOLVENT PROPERTIES
TESTING
TRANSITION ELEMENT COMPOUNDS
VANADATES
VANADIUM COMPOUNDS