Oxidative addition of zero-valent lanthanides at transition metal-halogen bonds

Journal Article · Thu Nov 20 04:00:00 EST 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00955399· OSTI ID:6476697

Suleimanov, G Z; Khandozhko, V N; Mekhdiev, R Yu; Petrovskii, P V; Kolobova, N E; Beletskaya, I P

Alkyl and aryl iodides add to zero-valent lanthanides to form Grignard-like reagents RLnI. The authors have already studied the addition of Ln(0) at the Hg-I bond in HgI/sub 2/ and RHgI compounds to give bimetallic derivatives of divalent lanthanides. In the present work, preliminary results are given for a study of the reactions of rare-earth elements with metal carbonyl halides with the general formula L(OC)/sub m/M-X (I), where L(OC)/sub m/M = Cp(OC)/sub 3/Cr, Cp(OC)/sub 3/Mo, Cp(OC)/sub 3/W, (OC)/sub 5/Mn, (OC)/sub 5/Re, or Cp(OC/sub 2/)Fe and X = Cl, BR, or I.

• Research Organization: M.V. Lomonosov Moscow State Univ., USSR
• OSTI ID: 6476697
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 35:5; ISSN BACCA
• Country of Publication: United States
• Language: Russian

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AROMATICS
BROMIDES
BROMINE COMPOUNDS
CARBON 13
CARBON ISOTOPES
CARBONYLS
CHEMICAL BONDS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
EVEN-ODD NUCLEI
FURANS
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENATED AROMATIC HYDROCARBONS
HETEROCYCLIC COMPOUNDS
HYDROGEN 1
HYDROGEN ISOTOPES
IODIDES
IODINATED ALIPHATIC HYDROCARBONS
IODINATED AROMATIC HYDROCARBONS
IODINE COMPOUNDS
ISOTOPES
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDATION
RARE EARTH COMPLEXES
RARE EARTH COMPOUNDS
SAMARIUM COMPLEXES
SAMARIUM COMPOUNDS
SAMARIUM IODIDES
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TETRAHYDROFURAN
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YTTERBIUM COMPLEXES
YTTERBIUM COMPOUNDS
YTTERBIUM IODIDES