Reaction of organotin iodides with metallic lanthanides

Journal Article · Wed Sep 10 04:00:00 EDT 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5354782

Bochkarev, L N; Kholodilova, M N; Zhil'tsov, S F; Guseva, T V; Bochkarev, M N; Razuvaev, G A

It is known that metallic lanthanides react readily with alkyl and aryl halides and form compounds similar to Grignard's reagents (RLnX). The authors found that organotin iodides react with metallic lanthanides in a similar manner. The compound Bu/sub 3/SnI reacts with ytterbium in THF solution at temperatures ranging from -50 to +20/sup 0/C, giving tributylstannylytterbium iodide Bu/sub 3/SNYbI, in 15-20% yield. The other products of the reaction are the distannane Bu/sub 3/SnSnBu/sub 3/ and YbI/sub 2/ which appear to form upon reaction between the original tributylin iodide and Bu/sub 3/SnYbI. Europium reacts with Bu/sub 3/SnI analogously.

• Research Organization: M. Gor'kii State Pedagogical Institute (USSR)
• OSTI ID: 5354782
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 56:3; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CHEMICAL REACTION YIELD
COMPLEXES
COMPLEXOMETRY
ELEMENTS
EUROPIUM
EUROPIUM COMPLEXES
EUROPIUM COMPOUNDS
EUROPIUM IODIDES
FURANS
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
IODIDES
IODINE COMPOUNDS
METALS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PRASEODYMIUM COMPOUNDS
PRASEODYMIUM IODIDES
RARE EARTH COMPLEXES
RARE EARTH COMPOUNDS
RARE EARTHS
SYNTHESIS
TETRAHYDROFURAN
TIN COMPOUNDS
TIN HALIDES
TIN IODIDES
YIELDS
YTTERBIUM
YTTERBIUM COMPLEXES
YTTERBIUM COMPOUNDS
YTTERBIUM IODIDES