Direct synthesis of arenepentamethylcyclopentadienyl ruthenium cations from ruthenium chloride (in Russian)
Journal Article
·
· Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
The authors have found that heating RuCl/sub 3/ x 3H/sub 2/O with pentamethylcyclopentadiene and an arene in alcohols such as methanol, ethanol, and propanol at reflux leads to the formation of (Ru(C/sub 5/Me/sub 5/)(arene))/sup +/ cations isolated as the tetrafluoroborides and hexafluorophosphates in 60-70% yield. This reaction is a rare example of the concurrent coordination of cyclopentadienyl and arene ligands with a transition metal.
- Research Organization:
- A.N. Nesmeyanov Institute of Heteroorganic Compounds, Moscow, USSR
- OSTI ID:
- 6476044
- Journal Information:
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Journal Issue: 2 Vol. 35:2; ISSN BACCA
- Country of Publication:
- United States
- Language:
- Russian
Similar Records
(Pentamethylcyclopentadienyl)ruthenium complexes. 6. (Pentamethylcyclopentadienyl)(polyarene)ruthenium cations. Synthesis and electrochemical reaction
(Hexamethylbenzene)ruthenium(II) complexes: synthesis and coordination chemistry of a novel tridentate ligand with an O,O,Cl donor set
Preparation and reactions of a cationic (. mu. sub 3 -methylidyne)ruthenium complex
Journal Article
·
Sun Dec 31 23:00:00 EST 1989
· Organometallics; (USA)
·
OSTI ID:6659540
(Hexamethylbenzene)ruthenium(II) complexes: synthesis and coordination chemistry of a novel tridentate ligand with an O,O,Cl donor set
Journal Article
·
Wed Oct 05 00:00:00 EDT 1988
· Inorg. Chem.; (United States)
·
OSTI ID:6236523
Preparation and reactions of a cationic (. mu. sub 3 -methylidyne)ruthenium complex
Journal Article
·
Wed Aug 01 00:00:00 EDT 1990
· Organometallics; (USA)
·
OSTI ID:6379558
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ALKANES
CATIONS
CHARGED PARTICLES
CHEMICAL REACTION YIELD
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
COMPLEXOMETRY
CYCLOALKANES
HALIDES
HALOGEN COMPOUNDS
HEATING
HYDRATES
HYDROCARBONS
HYDROXY COMPOUNDS
IONS
LIGANDS
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC SOLVENTS
REFRACTORY METAL COMPOUNDS
RUTHENIUM CHLORIDES
RUTHENIUM COMPLEXES
RUTHENIUM COMPOUNDS
SOLVENTS
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ALKANES
CATIONS
CHARGED PARTICLES
CHEMICAL REACTION YIELD
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
COMPLEXOMETRY
CYCLOALKANES
HALIDES
HALOGEN COMPOUNDS
HEATING
HYDRATES
HYDROCARBONS
HYDROXY COMPOUNDS
IONS
LIGANDS
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC SOLVENTS
REFRACTORY METAL COMPOUNDS
RUTHENIUM CHLORIDES
RUTHENIUM COMPLEXES
RUTHENIUM COMPOUNDS
SOLVENTS
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS