Preparation and reactions of a cationic (. mu. sub 3 -methylidyne)ruthenium complex
- Tokyo Institute of Technology (Japan)
The reaction of (({eta}{sup 5}-C{sub 5}Me{sub 5})RuCl{sub 2}){sub 2} (1) with AgBF{sub 4} in ethanol yields the cationic {mu}{sub 3}-methylidyne complex ((({eta}{sup 5}-C{sub 5}Me{sub 5})Ru){sub 3}({mu}{sub 2}-Cl){sub 2}({mu}{sub 2}-H)({mu}{sub 3}-CH))(BF{sub 4}) (2), which undergoes reductive coupling between {mu}{sub 3}-methyne and {mu}{sub 2}-hydride ligands to give (({eta}{sup 5}-C{sub 5}Me{sub 5})Ru(CO)({mu}{sub 2}CH{sub 2})({mu}{sub 2}-Cl)Ru(CO)({eta}{sup 5}-C{sub 5}Me{sub 5}))(BF{sub 4}) (4) upon treatment with carbon monoxide. Molecular structures of 2 and 4 determined by x-ray diffraction studies are described.
- OSTI ID:
- 6379558
- Journal Information:
- Organometallics; (USA), Journal Name: Organometallics; (USA) Vol. 9:8; ISSN 0276-7333; ISSN ORGND
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
COHERENT SCATTERING
COMPLEXES
DATA
DATA ANALYSIS
DIFFRACTION
EXPERIMENTAL DATA
INFORMATION
MEASURING INSTRUMENTS
MEASURING METHODS
MOLECULAR STRUCTURE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
RUTHENIUM COMPLEXES
SCATTERING
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
X-RAY DIFFRACTION
400201* -- Chemical & Physicochemical Properties
COHERENT SCATTERING
COMPLEXES
DATA
DATA ANALYSIS
DIFFRACTION
EXPERIMENTAL DATA
INFORMATION
MEASURING INSTRUMENTS
MEASURING METHODS
MOLECULAR STRUCTURE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
RUTHENIUM COMPLEXES
SCATTERING
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
X-RAY DIFFRACTION