Complex ion chemistry. Progress report No. 2, July 1, 1969-June 30, 1970
Investigations undertaken during this report period are: (1) syntheses and characterization of 8 chromium and 2 cobalt complexes; aquation, anation, base hydrolysis and isomerization reactions of cobalt, iridium, and chromium complexes; redox reactions of cobalt and chromium complexes. The following new complexes were synthesized and their absorption spectra reported: (1) Tetraaquo(1-azonia-4,7-diazaheptane)chromium(III) Cation; (2) Pentaaquo(1,7-diazonia-4-azaheptane)chromium(III) Cation or Pentaaquo(1,4-diazonia-7-azaheptane)chromium(III) Cation; (3) Aquotetraethylenepentaamine Complexes of Chromium(III) with a Partially Unwrapped Tetren Ligand; (4) Aquotriethylenetetraamine Complexes of Chromium(III) with a Partially Unwrapped Trien Ligand; (5) cis- and trans-Dichlorotriaquoamminechromium(III) Cations; (6) Blue-Violet Chlorotetraaquoamminechromium(III) Cation; (7) Chloroaquobis(2,2'-dipyridyl)chromium(III) Cation; (8) Chloroaquodiethylenetriamine Complexes of Cobalt(III); (9) A Sulfatodiethylenetriamine Complex of Cobalt(III); and (10) ..cap alpha..BR- and ..cap alpha..BS-Acidotetraethylenepentaaminecobalt(III) Cations.
- Research Organization:
- University of Southern California, Los Angeles (USA). Dept. of Chemistry
- DOE Contract Number:
- AT03-76SF80034
- OSTI ID:
- 6467918
- Report Number(s):
- UCLA-34P170-11
- Country of Publication:
- United States
- Language:
- English
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ABSORPTION SPECTRA
AMINES
CHEMICAL REACTIONS
CHROMIUM COMPLEXES
COBALT COMPLEXES
COMPLEXES
DECOMPOSITION
DIAZO COMPOUNDS
ELECTRON TRANSFER
HYDRATES
HYDROLYSIS
IRIDIUM COMPLEXES
ISOMERIZATION
LIGANDS
LYSIS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
REDUCTION
RESEARCH PROGRAMS
SOLVOLYSIS
SPECTRA
SYNTHESIS
TRANSITION ELEMENT COMPLEXES