Complex ion chemistry. Progress report No. 16, July 1, 1968-December 31, 1968 and progress report No. 1, January 1, 1969-June 30, 1969
Investigations undertaken during this report period are: (1) syntheses and absorption spectra of chromium and cobalt complexes; (2) aquation, anation, base hydrolysis, and isomerization reactions of iridium, chromium and cobalt complexes; (3) redox reaction of 1,2,3-Co(dien) (OH/sub 2/)/sub 3//sup 3 +/ amd water; (4) decomposition of cis- and trans Dichlorobis(ethylenediamine)chromium chloride in 2-Methoxyethanol. The following new complexes were synthesized: (1) Tetraaquo(1-azonia-4,7-diazaheptane)chromium(III) Cation; (2) Pentaaquo(1,7-diazonia-4-azaheptane)chromium(III) Cation; or Pentaaquo(1,4-diazonia-7-azaheptane)chromium(III) Cation; (3) Aquotetraethylenepentaamine Complexes of Chromium(III) with a Partially Unwrapped Tetren Ligand; (4) Aquotriethylenetetraamine Complexes of Chromium(III) with a Partially Unwrapped Trien Ligand; (5) cis- and trans-Dichlorotriaquoamminechromium(III) Cations; (6) Blue-violet Chlorotetraaquoamminechromium(III) Cation; (7) Chloroaquodiethylenetriamine Complexes of Cobalt(III); and (8) A Sulfatodiethylenetriamine Complex of Cobalt(III).
- Research Organization:
- University of Southern California, Los Angeles (USA). Dept. of Chemistry
- DOE Contract Number:
- AT03-76SF80034
- OSTI ID:
- 6324462
- Report Number(s):
- UCLA-34P12-73; UCLA-34P170-4; ON: DE81024191
- Country of Publication:
- United States
- Language:
- English
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Complex ion chemistry. Progress report No. 3, July 1, 1970-June 30, 1971
Related Subjects
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ABSORPTION SPECTRA
AMINES
CHEMICAL REACTIONS
CHROMIUM COMPLEXES
COBALT COMPLEXES
COMPLEXES
DECOMPOSITION
DIAZO COMPOUNDS
HYDRATES
HYDROLYSIS
IRIDIUM COMPLEXES
ISOMERIZATION
LYSIS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
REDOX REACTIONS
RESEARCH PROGRAMS
SOLVOLYSIS
SPECTRA
SYNTHESIS
TRANSITION ELEMENT COMPLEXES