Theoretical model for two-layer metal-dielectric film growth
Journal Article
·
· Appl. Phys. Commun.; (United States)
OSTI ID:6463910
A theoretical model for the growth on metal surfaces of dielectric films such as metal oxides, halides, or sulfides is presented. The model consists of a thin compact layer and a thicker porous layer which grows by recrystallization of the compact layer. Cases are considered in which growth is limited by metal ion diffusion or electron tunneling through the compact layer. The corresponding kinetic differential equations are solved analytically and the results are in agreement with recent film growth data. The model has applicability in corrosion studies as well as in passivation anode film growth in batteries.
- Research Organization:
- Solar Energy Research Inst., Golden, CO
- OSTI ID:
- 6463910
- Journal Information:
- Appl. Phys. Commun.; (United States), Journal Name: Appl. Phys. Commun.; (United States) Vol. 1:1; ISSN APCOD
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
25 ENERGY STORAGE
250903 -- Energy Storage-- Batteries-- Materials
Components
& Auxiliaries
36 MATERIALS SCIENCE
360105* -- Metals & Alloys-- Corrosion & Erosion
ALKALI METAL COMPOUNDS
ANODES
CHARGED PARTICLES
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
CORROSION
DIELECTRIC MATERIALS
DIFFUSION
DIMENSIONS
ELECTRIC BATTERIES
ELECTROCHEMICAL CELLS
ELECTRODES
ELEMENTS
FILMS
HALIDES
HALOGEN COMPOUNDS
IONS
LAYERS
LITHIUM CHLORIDES
LITHIUM COMPOUNDS
LITHIUM HALIDES
MATERIALS
MATHEMATICAL MODELS
METALS
RECRYSTALLIZATION
SURFACES
THICKNESS
250903 -- Energy Storage-- Batteries-- Materials
Components
& Auxiliaries
36 MATERIALS SCIENCE
360105* -- Metals & Alloys-- Corrosion & Erosion
ALKALI METAL COMPOUNDS
ANODES
CHARGED PARTICLES
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
CORROSION
DIELECTRIC MATERIALS
DIFFUSION
DIMENSIONS
ELECTRIC BATTERIES
ELECTROCHEMICAL CELLS
ELECTRODES
ELEMENTS
FILMS
HALIDES
HALOGEN COMPOUNDS
IONS
LAYERS
LITHIUM CHLORIDES
LITHIUM COMPOUNDS
LITHIUM HALIDES
MATERIALS
MATHEMATICAL MODELS
METALS
RECRYSTALLIZATION
SURFACES
THICKNESS