Modeling heterogeneous catalysts with homogeneous catalysts. Comparison of catalytic exchange of deuterium for hydrogen at the. cap alpha. and. beta. positions of tertiary amines by using either palladium black or Ru/sub 3/(CO)/sub 12/

Journal Article · Wed May 06 04:00:00 EDT 1981 · J. Am. Chem. Soc.; (United States)

DOI:https://doi.org/10.1021/ja00399a077· OSTI ID:6455253

Shvo, Y; Thomas, D W; Laine, R M

This paper describes the catalytic activation of the ..cap alpha.. and ..beta.. C-H bonds of triethylamine (Et/sub 3/N), tri-n-propylamine (Pr/sub 3/N), and tri-n-butylamine (Bu/sub 3/N) with the heterogeneous catalyst, palladium black, and several homogeneous catalysts deriving from group 8 metal carbonyl complexes. The homogeneous catalysts, in particular the system based on Ru/sub 3/-(CO)/sub 12/, can be used to model the catalytic actions of palladium black for five different reaction parameters in two related catalytic reactions.

• Research Organization: SRI International, Menlo Park, CA
• OSTI ID: 6455253
• Journal Information: J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 103:9; ISSN JACSA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400303* -- Organic Chemistry-- Isotope Exchange & Isotope Separation-- (-1987)
AMINES
CARBONYLS
CATALYSTS
CATALYTIC EFFECTS
DATA
DEUTERIUM
ELEMENTS
EXPERIMENTAL DATA
HYDROGEN ISOTOPES
INFORMATION
ISOTOPES
ISOTOPIC EXCHANGE
LIGHT NUCLEI
METALS
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
PALLADIUM
PLATINUM METALS
POWDERS
REFRACTORY METALS
RHODIUM
RHODIUM COMPOUNDS
RUTHENIUM COMPOUNDS
STABLE ISOTOPES
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS